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ChemInform Abstract: Total Synthesis of Archaeal 36-Membered Macrocyclic Diether Lipid.

✍ Scribed by T. EGUCHI; K. ARAKAWA; T. TERACHI; K. KAKINUMA

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Total Synthesis of Archaeal 36-Membered Macrocyclic Diether Lipid.

-The synthesis of the title lipid (I) is based on stereoselective preparation of functionalized isoprenoid chains, ether-linkage formation between these chains with a glycerol derivative, and the ultimate intramolecular dicarbonyl coupling using low-valent titanium McMurry coupling as key steps. -(EGUCHI, T.;

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