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ChemInform Abstract: Total Synthesis of an Enantiomeric Pair of FR900482. Part 2. Syntheses of the Aromatic and the Optically Active Aliphatic Segments.

✍ Scribed by T. YOSHINO; Y. NAGATA; E. ITOH; M. HASHIMOTO; T. KATOH; S. TERASHIMA

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Total Synthesis of an Enantiomeric Pair of FR900482. Part 2. Syntheses of the Aromatic and the Optically Active Aliphatic Segments.

-The aromatic segment (II) is prepared by a facile synthetic pathway from the commercially available acid (I). Both enantiomers of the aliphatic segment (IV) are synthesized in enantiomerically pure form by employing the corresponding tartrate as the chiral starting material for the preparation of the parent compound (III) by a literature method. -(YOSHINO, T.; NAGATA,

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