✦ LIBER ✦

ChemInform Abstract: Total Synthesis of (+)-Alexine by Utilizing a Highly Stereoselective [3 + 2] Annulation Reaction of an N-Tosyl-α-amino Aldehyde and a 1,3-Bis(silyl)propene.

✍ Scribed by Martina Dressel; Per Restorp; Peter Somfai

Publisher: John Wiley and Sons
Year: 2008
Weight: 18 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200833199

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Total Synthesis of (+)-Alexine by Utiliz

Total Synthesis of (+)-Alexine by Utilizing a Highly Stereoselective [3+2] Annulation Reaction of an N-Tosyl-α-Amino Aldehyde and a 1,3-Bis(silyl)propene

✍ Martina Dressel; Per Restorp; Peter Somfai 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 1 views

## Abstract A novel route towards the polyhydroxylated pyrrolizidine alkaloid (+)‐alexine has been developed. A key step in this synthesis is a highly stereoselective [3+2] annulation reaction of __N__‐Ts‐α‐amino aldehyde **7 a** (Ts=tosyl) and 1,3‐bis(silyl)propene **8 a** for the construction of

Stereoselective Synthesis of Functionali

Stereoselective Synthesis of Functionalized Pyrrolidines via a [3 + 2]-Annulation of N-Ts-α-Amino Aldehydes and 1,3-Bis(silyl)propenes.

✍ Per Restorp; Andreas Fischer; Peter Somfai 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

ChemInform Abstract: Lewis Acid Promoted

ChemInform Abstract: Lewis Acid Promoted Hetero [2 + 2] Cycloaddition Reactions of Aldehydes with 10-Propynyl-9(10H)-acridone. A Highly Stereoselective Synthesis of Acrylic Acid Derivatives and 1,3-Dienes Using an Electron Deficient Variant of Ynamine.

✍ Richard P. Hsung; Craig A. Zificsak; Lin-Li Wei; Christopher J. Douglas; Hui Xio 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views