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ChemInform Abstract: Total Synthesis and Absolute Structure of Manzacidin A and C.

โœ Scribed by Kosuke Namba; Tetsuro Shinada; Toshiyuki Teramoto; Yasufumi Ohfune

Publisher
John Wiley and Sons
Year
2001
Weight
35 KB
Volume
32
Category
Article
ISSN
0931-7597

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Total Synthesis and Absolute Configuration of Polycavernoside A. -The first total synthesis of polycavernoside A (XII), a toxin of red alga species, is presented, involving formation of the cyclic acetal (IV), lactonization of secoic acid (V) and rearrangement of the obtained 12-membered lactone (V