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ChemInform Abstract: Total Synthesis and Absolute Configuration of the Guaiane Sesquiterpene Englerin A.

✍ Scribed by Matthieu Willot; Lea Radtke; Daniel Koenning; Roland Froehlich; Viktoria H. Gessner; Carsten Strohmann; Mathias Christmann

Publisher
John Wiley and Sons
Year
2010
Weight
19 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Total Synthesis and
ChemInform Abstract: Total Synthesis and Absolute Configuration of Polycavernoside A.
✍ K. FUJIWARA; A. MURAI; M. YOTSU-YAMASHITA; T. YASUMOTO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 38 KB πŸ‘ 1 views

Total Synthesis and Absolute Configuration of Polycavernoside A. -The first total synthesis of polycavernoside A (XII), a toxin of red alga species, is presented, involving formation of the cyclic acetal (IV), lactonization of secoic acid (V) and rearrangement of the obtained 12-membered lactone (V