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ChemInform Abstract: Total Syntheses of (Sp)-(+)- and (Rp)-(-)-Spiniferin-1, a Pair of Unusual Natural Products with Planar Chirality

✍ Scribed by Yun-Shan Sun; Kai Ding; Wei-Sheng Tian


Publisher
John Wiley and Sons
Year
2011
Weight
37 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

via a palladium‐catalyzed β‐H elimination reaction of ester (I) and a perfluorobutanesulfonyl fluoride induced homoallylic carbocation rearrangement as key steps