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ChemInform Abstract: Titanocene(II)-Promoted Desulfurizative Acylation of Thioacetals with Alkanenitriles.

✍ Scribed by Takeshi Takeda; Haruhiko Taguchi; Tooru Fujiwara

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Titanocene(II)-Promoted Reaction of Thioacetals with Alkynes: Highly Stereoselective Preparation of Conjugated Dienes. -Reaction of titanium species, prepared by desulfurizative titanation of thioacetals (I), with symmetrical alkynes (II) affords the conjugated dienes (III) in good yields. When an