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ChemInform Abstract: Titanium(IV) Chloride Induced Reactions of Ketones and C-Acylimines with Dimethylcyanamide.

✍ Scribed by M. MAZIK; R. BOESE; R. SUSTMANN

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Titanium(IV) Chloride Induced Reactions of Ketones and C-Acylimines with Dimethylcyanamide.

-The product distribution in the reactions of ketones (I) and (V) with dimethylcyanamide (II) is strongly influenced by the methyl group at the phenyl ring. Acylimines (VIII) give the monoadducts (IX), exclusively. In the case of the isopropyl derivative (X) a multistep cyclization is observed.

📜 SIMILAR VOLUMES

Titanium(IV) Chloride Induced Reactions
Titanium(IV) Chloride Induced Reactions of Ketones andC-Acylimines with Dimethylcyanamide
✍ Mazik, Monika ;Sustmann, Reiner ;Boese, Roland 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 730 KB

## Abstract The reactions of ketones (benzophenone, 4‐methylbenzophenone, acetophenone, acetone, and 2,2,4,4‐tetramethyl‐3‐pentanone) and __C__‐acylimines with dimethylcyanamide in the presence of titanium(IV) chloride were investigated, Benzophenone and 4‐methylbenzophenone react with dimethylcyan