ChemInform Abstract: TiCl3(OTf) and TiO(TFA)2, Efficient Catalysts for Ring Opening of Epoxides with Alcohols, Acetic Acid, and Water.
β Scribed by Nasser Iranpoor; Behzad Zeynizadeh
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
TiCl 3 (OTf ) and TiO(TFA) 2 , Efficient Catalysts for Ring Opening of Epoxides with Alcohols, Acetic Acid, and Water.
-High stereoand regioselectivity, non-toxicity and stability of the catalysts, easy work-up, high yields, and short reaction times make the method given a useful addition to known procedures for the ring opening of epoxides.
-(IRANPOOR,
π SIMILAR VOLUMES
Conversion of Epoxides to Thiiranes Catalyzed with TiO(TFA) 2 and TiCl 3 (OTf ) in the Presence of Ammonium Thiocyanate or Thiourea. -TiO(O-CO-CF 3 ) 2 and TiCl 3 (O-Tf) prove to be efficient catalysts for the conversion of epoxides to thiiranes with both NH 4 SCN or thiourea under aprotic conditio
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