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ChemInform Abstract: Through-Space 13C—19F Coupling Can Reveal Conformations of Modified BODIPY Dyes.

✍ Scribed by Jiong Chen; Joe Reibenspies; Agnes Derecskei-Kovacs; Kevin Burgess


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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Conformational dynamics of bis(BF2)-2,2′
✍ X. Xie; Y. Yuan; R. Krüger; M. Bröring 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB

## Abstract The conformation of [bis‐(__N__,__N__′‐difluoroboryl)]‐3,3′‐diethyl‐4,4′,8,8′,9,9′,10,10′‐octamethyl‐2,2′‐bidipyrrin (1) in solution was studied by analyzing the ^13^C^19^F and ^19^F^19^F through‐space spin–spin couplings. The ^1^H and ^13^C NMR spectra were assigned on the basis of n