## Abstract The reaction of thiobenzophenone (= diphenylmethanethione; 8a) or 9__H__‐fluorene‐9‐thione (8b) and methyl fumarate (9) in excess PhN~3~ at 80° yields a mixture of diastereoisomeric thiiranes 10 and 11 (__Scheme 1__). A mechanism involving the initial formation of 1‐phenyl‐4, 5‐dihydro‐
✦ LIBER ✦
ChemInform Abstract: “Three-Component Reaction” with Aromatic Thioketones, Phenyl Azide, and Dimethyl Fumarate.
✍ Scribed by G. MLOSTON; J. ROMANSKI; A. LINDEN; H. HEIMGARTNER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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