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ChemInform Abstract: Thio-Claisen Rearrangement Used in Preparing anti-β-Functionalized γ,δ-Unsaturated Amino Acids: Scope and Limitations.

✍ Scribed by Zhihua Liu; Sukeshi J. Mehta; Kwang-Soo Lee; Bryan Grossman; Hongchang Qu; Xuyuan Gu; Gary S. Nichol; Victor J. Hruby

Book ID
112044754
Publisher
John Wiley and Sons
Year
2012
Weight
57 KB
Volume
43
Category
Article
ISSN
0931-7597

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Novel anti-β-functionalized γ,δ-unsatura
Novel anti-β-functionalized γ,δ-unsaturated amino acids via a thio–Claisen rearrangement
✍ Zhihua Liu; Hongchang Qu; Xuyuan Gu; Kwang-Soo Lee; Bryan Grossman; Vlad K. Kumi 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 358 KB

A significantly improved thio-Claisen rearrangement method was developed for preparing anti-b-functionalized c,d-unsaturated amino acids, which are extremely useful nonproteinogenic amino acids used in chemistry and biology research. The mild reaction condition successfully introduced base labile fu