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ChemInform Abstract: Thiele′s Acid Revisited: Isolation and Characterization of Two Minor Products Formed by Carbonation of Cyclopentadienide Anion.

✍ Scribed by A. P. MARCHAND; I. N. N. NAMBOOTHIRI; S. B. LEWIS


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Thiele's Acid Revisited: Isolation and Characterization of Two Minor Products Formed by Carbonation of Cyclopentadienide Anion. -Two minor products (V) and (VI) of the formerly described Diels-Alder dimerization of cyclopentadienecarboxylic acid leading to Thiele's acid (IV) are isolated and characterized. Intramolecular [2 + 2] photocyclization of (VI) affords (VII). -(MARCHAND, A.