𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Thermal Rearrangement of 3-Trimethylsilyl-1-pyrazoline.

✍ Scribed by Y.-W. KWAK; S.-H. PARK; H.-S. KIM

Book ID
112039503
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

A theoretical study of thermal [1,3]-sig
A theoretical study of thermal [1,3]-sigmatropic rearrangements of 3-trimethylsilyl-1-pyrazoline: Concerted vs. stepwise mechanisms
✍ Chultack Lim; Hee Soon Lee; Young-Woo Kwak; Cheol Ho Choi πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 421 KB

## Abstract Possible reaction mechanisms of 1,3‐silyl and 1,3‐hydrogen thermal rearrangements of trimethylsilyl‐1‐pyrazoline and its model systems were theoretically explored using B3LYP, MP2, CR‐CCSD(T), CASSCF(6,5), and MRMP2(6,5) theories. Nitrogen substitution at the center position of allylic