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ChemInform Abstract: Thermal Intramolecular [4 + 2] Cycloadditions of Allenamides: A Stereoselective Tandem Propargyl Amide Isomerization—Cycloaddition.

✍ Scribed by Andrew G. Lohse; Richard P. Hsung

Publisher
John Wiley and Sons
Year
2009
Weight
31 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: High-Pressure Promo
ChemInform Abstract: High-Pressure Promoted Stereoselective Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes and Enol Ethers.
✍ R. M. UITTENBOGAARD; J.-P. G. SEERDEN; H. W. SCHEEREN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

High-Pressure Promoted Stereoselective Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes and Enol Ethers. -The tandem cycloadditions of the nitroalkenes (I) and (V) with ethyl vinyl ether are found to be strongly accelerated under high pressure. The reactions proceed regioand stereoselectively.