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ChemInform Abstract: Thermal Cycloaddition Reaction of Symmetrical and Unsymmetrical α-Diazo-β-diketones with 4-Aryl-2-methyl-2,3-dihydro-1,5-benzothia/diazepines.

✍ Scribed by Jiaxi Xu; Sheng Jin


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Thermal cycloaddition reaction of symmet
✍ Jiaxi Xu; Sheng Jin 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 193 KB 👁 1 views

Symmetrical and unsymmetrical ␣-diazo-b-diketones undergo thermal Wolff rearrangements to generate ␣-carbonylketenes to participate as dienes in Diels-Alder reactions with 4-aryl-2-methyl-2,3-dihydro-1,5-benzothia/diazepines to give, where applicable, regiospecific cycloadducts, 4a,5,6,12tetrahydro