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ChemInform Abstract: Thermal Cyclization of 1-{(Z)-1-Hexene-3,5-diynyl}-2-(1,3-butanediynyl)benzene Leading to Dinaphtho[1,2-b:2,1-f]semibullvalene and Dinaphtho[2,1-b:1,2-j]elassovalene Skeletons via Cyclobuta[a]naphthalene.

โœ Scribed by T. KAWANO; C. IKEMOTO; I. UEDA

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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Cycloaromatization of a Non-Conjugated Polyenyne System: Synthesis of 5H-Benzo(d)fluoreno(3,2-b)pyrans via Diradicals Generated from 1-(2-(4-(2-Alkoxymethylphenyl)butan-1,3diynyl))phenylpentan-2,4-diyn-1-ols and Trapping Evidence for the 1,2-Didehydrobenzene Diradical. -Mild thermolysis of the tetr