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ChemInform Abstract: Thermal and Photochemical Reactions of Aluminum, Gallium, and Indium Atoms (M) in the Presence of Ammonia: Generation and Characterization of the Species M×NH3, HMNH2, MNH2 and H2MNH2.

✍ Scribed by Hans-Joerg Himmel; Anthony J. Downs; Tim M. Greene

Publisher: John Wiley and Sons
Year: 2001
Weight: 34 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200103016

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Matrix Reactivity of Al and Ga Atoms (M) in the Presence of Silane: Generation and Characterization of the η2-Coordinated Complex M⋅SiH4, the Insertion Product HMSiH3, and the MI Species MSiH3 in a Solid Argon Matrix

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## Abstract Matrix isolation experiments give evidence for the formation of the loosely bonded metal–silane complex M⋅SiH~4~ by the spontaneous reaction of Al or Ga atoms (M) with silane in a solid Ar matrix at 12 K; however, Ga~2~ appears to insert spontaneously into an SiH bond to form HGaGaSiH~