Singlet Oxygen in the Photodegradation of Lignin Models. -The photochemical behavior of model compounds (I) and (II), resembling the fundamental bonding patterns of lignin, is studied. The softwood-like aryl ethers (Ia), (Ic), and (IIa) and the hardwood-like model (Ib) give under photochemical oxid
ChemInform Abstract: Theoretical Models for the Selectivity of Organic Singlet and Triplet Photoreactions
✍ Scribed by M. KLESSINGER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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st oxidative addition reactions to alkane C-H bonds. In contrast, a lighter transition-metal Ž . center i.e., the second row will result in a larger ⌬ E and then tend to undergo the st reductive elimination reactions of the C-H bond-forming. The results obtained are in good agreement with the availa