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ChemInform Abstract: Theoretical Investigation of the Mechanism of cis—trans Regulation for the Allylnickel(II)-Catalyzed 1,4 Polymerization of Butadiene

✍ Scribed by Sven Tobisch


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
33
Category
Article
ISSN
0931-7597

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✍ Peter Cass; Kerry Pratt; Terry Mann; Bob Laslett; Ezio Rizzardo; Robert Burford 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB 👁 1 views

The catalytic system Co/methylaluminoxane/tert-butyl chloride has been studied and optimized for the polymerization of 1,3-butadiene to high cis-1,4-polybutadiene. The ratio of the individual catalyst components was investigated to achieve maximum conversion, stereoregularity, and molecular weight.