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ChemInform Abstract: The Versatile Behavior of a 1,2λ5-Azaphosphete Towards Protic Nucleophiles.

✍ Scribed by G. BOUHADIR; K. BIEGER; P. LIVOTTO; R. REAU; H. GORNITZKA; F. DAHAN; G. BERTRAND

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199735210

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✦ Synopsis

The Versatile Behavior of a 1,2λ5-Azaphosphete Towards Protic Nucleophiles. -Different behavior of (I) is observed in the title reactions. Whereas amines lead to five-membered phosphazenes, phenols and thiophenols yield linear phosphazenes.

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## 25 -204 1,1,1,4,5,5,5-Heptafluoro-4-(trifluoromethyl)-2,3-pentanedione, a Potent Reagent for the Synthesis of Cyclic λ 5 σ 5 Phosphoranes. -Title compound (II) is employed for the convenient and high-yielding synthesis of cyclic phosphoranes (III). No interaction of the diketone (II) with the i