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ChemInform Abstract: The Total Synthesis of Eleutherobin: A Surprise Ending.

✍ Scribed by X.-T. CHEN; B. ZHOU; S. K. BHATTACHARYA; C. E. GUTTERIDGE; T. R. R. PETTUS; S. J. DANISHEFSKY

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Total Synthesis of Eleutherobin: A Surprise Ending.

-Key step in the synthesis of the title compound, a potent antitumor agent showing the same modality of action as paclitaxel, is a modified Stille coupling to connect the aglycon and the carbohydrate which is employed due to low diastereoselectivities observed in conventional glycosidation reactions (most yields not given exactly). -(CHEN, X.-T.;

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