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ChemInform Abstract: The Synthesis of β-N-Tosylamino Hydroxylamines via the Ring Opening of N-Tosylaziridines and Their Use in Reverse Cope Cyclizations.

✍ Scribed by Ian A. O'Neil; J. Chris Woolley; J. Mike Southern; Heather Hobbs


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Ring-Opening of N-T
✍ Hans-Joachim Breternitz; Ernst Schaumann 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Ring-Opening of N-Tosylaziridines by Heterosubstituted Allyl Anions. Application to the Synthesis of Azetidines and Pyrrolidines. -Aziridines (II) and (V) undergo ring opening in the presence of in situ generated silyl-or sulfur-substituted allyl anions to give the desired ring-opened products. Pro