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ChemInform Abstract: The Synthesis of Octosyl Nucleosides Based on Intramolecular Oxyselenation of a Conjugated Diene.

✍ Scribed by K. HARAGUCHI; M. HOSOE; H. TANAKA; S. TSURUOKA; K. KANMURI; T. MIYASAKA

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Synthesis of Octosyl Nucleosides Based on Intramolecular Oxyselenation of a Conjugated Diene.

-A new stereoselective ring construction for 3,7-anhydrooctofuranosyl nucleoside is performed by 6-endo-trig oxyselenation of the conjugated diene (I). The resulting compound is considered as a versatile synthon for the synthesis of octosyl nucleoside antibiotics, demonstrated by the preparation of protected nikkomycin Sz (IV). -(HARAGUCHI, K.;

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