A new pathway for the reaction involving an ␣-haloketone and a dialkyl phosphite has been suggested, It offers a highly stereoselective synthetic procedure leading to b-haloenol phosphates in one-pot reactions that take place in good yields. However, normal Pudovik reaction products were formed when
✦ LIBER ✦
ChemInform Abstract: The Stereoselective Synthesis of β-Haloenol Phosphates — A Reinvestigation of the Reaction of α-Haloketones with Diethyl Phosphite.
✍ Scribed by Yixiang Ding; Xiaogen Huang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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