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ChemInform Abstract: The Stabilization of Lithiated Organic Compounds by Water as a Ligand — Synthesis of a New Lithium—Imidazole Complex and Regioselective Reactions with Selected Electrophiles.

✍ Scribed by J. ATZRODT; R. BECKERT; M. BRAEUER; K. NORDHOFF; E. ANDERS; H. GOERLS


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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The Stabilization of Lithiated Organic C
✍ Jens Atzrodt; Rainer Beckert; Michael Bräuer; Karsten Nordhoff; Ernst Anders; He 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB 👁 2 views

The deprotonation of the 4H-imidazoles 1 by lithium hydride Alkylation, as well as acylation, of 2 leads to the exocyclic substituted derivatives 3 and 5. The NMR spectra of 3 and 5 yields the lithiated derivatives 2 which contain a stable delocalized anion. Surprisingly, the X-ray crystal structure