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ChemInform Abstract: The Rotational Isomerism of the Disilanes Me—SiX2—SiX2—Me (X = —H, —F, —Br, —I): A Combined ab initio and Raman Spectroscopic Study

✍ Scribed by Robert Zink; Karl Hassler


Publisher
John Wiley and Sons
Year
2000
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ Anke Jähn; Karla Schenzel; Robert Zink; Karl Hassler 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB 👁 1 views

The Raman vibrational spectra of the heptamethyltrisilanes with X = H, F, Cl, Br, XMe 2 SiSiMe 2 SiMe 3 , C 6 H 5 and unambiguously prove the presence of two rotamers, anti and gauche, in the liquid state. With variable-OCH 3 , temperature Raman vibrational spectroscopy, enthalpy di †erences between