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ChemInform Abstract: The Role of Cyclobutenes in Gold(I)-Catalyzed Skeletal Rearrangement of 1,6-Enynes.

✍ Scribed by Escribano-Cuesta, Ana; Perez-Galan, Patricia; Herrero-Gomez, Elena; Sekine, Masaki; Braga, Ataualpa A. C.; Maseras, Feliu; Echavarren, Antonio M.

Book ID
118756839
Publisher
John Wiley and Sons
Year
2013
Weight
38 KB
Volume
44
Category
Article
ISSN
0931-7597

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Gold(I)-Catalyzed Cyclizations of 1,6-En
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The authors have recently found that the configuration of diene 64 (Ar = p-MeOC 6 H 4 ) in Scheme 6 was incorrectly assigned. The major isomer has a cis configuration, whereas the configuration of related compounds 62 and 66 (Ar = Ph and p-O 2 NC 6 H 4 ) is trans as reported. The correct configurati