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ChemInform Abstract: The Regiospecific C-3 Lithiation of 5-Ethyl-2-furoic Acid: An Approach to Key Natural Product Intermediates.

โœ Scribed by P. J. PERRY; V. H. PAVLIDIS; M. NAIK


Book ID
112039823
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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The Regiospecific C-3 Lithiation of 5-Et
โœ Philip J. Perry; Vasilios H. Pavlidis; Manisha Naik ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 340 KB

Treatment of 5ethyl-2-furoic acid with n-butyllithium in tetrahydrofuran gave regiospecific C-3 lithiation, whereas treatment of the same acid with lithium di-isopropylamide (LDA) afforded only starting material. The synthetic utility of dilithiated 5-ethyl-2-furoic acid has been demonstrated with t