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ChemInform Abstract: The Reaction of Wittig and Wittig—Horner Reagents and Alkyl Phosphites with 1,2-Naphthoquinone-1-benzimide.

✍ Scribed by Mona H. N. Arsanious

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Reaction of Wittig and Wittig-Horner Reagents and Alkyl Phosphites with 1,2-Naphthoquinone-1-benzimide.

-In order to determine the preferential site of attack of organophosphorus reagents towards quinone imines, the action of phosphonium ylides (II), the anions of phosphonoacetates (V), and alkyl phosphite on the title compound (I) is examined. A new pattern of Wittig reagents (II) is discovered as well as an establishment of a novel method for the synthesis of new phosphonate products using Wittig-Horner reagents (V). Towards alkyl phosphites, (I) behaves in a manner different from that of the title reagents. -(ARSANIOUS,

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