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ChemInform Abstract: The Reaction of Trivalent Phosphorus Compounds with 1,2-Dioxetanes and 1,2-Dioxolanes

โœ Scribed by P. C. VASQUEZ; Y.-X. CHEN; A. L. BAUMSTARK

Book ID
112034788
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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โœ Alfons L. Baumstark; Pedro C. Vasquez; Yaxiong Chen ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 400 KB

The reaction of a series of 4,4-dimethyl-3,5,5-(R3, R2, ## RI)-3-hydroxy-I,2-dioxolanes la-d [la (R, with trimethyl phosphite or triphenylphosphine produced the p-hydro.xy ketones, 2a-d [(R,R#70H)CMe2-COR3], and the corresponding phosphoryl compounds in high yield. The reactions were slow (-24 ho