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ChemInform Abstract: The Reaction of the α-Selenium Stabilized Copper Reagents ArSeCH2Cu(CN)ZnCl with Aldehydes.

✍ Scribed by De-Hui Duan; Xian Huang

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

1999 organo-selenium compounds, isocyclic C derivatives organo-selenium compounds, isocyclic C derivatives S 0134

25 -159

The Reaction of the α-Selenium Stabilized Copper Reagents ArSeCH 2 Cu(CN)ZnCl with Aldehydes.

-Copper reagent (III) reacts in the presence of a Lewis acid with aromatic and aliphatic aldehydes to furnish the α-selenium functionalized secondary alcohols (V) in good yields. However, ketones remain almost unreacted. The Lewis acid can play an important role as in the case of the α,β-unsaturated aldehyde acrolein (VI). -(DUAN,

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