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ChemInform Abstract: The Reaction of Aromatic Dialdehydes with Enantiopure 1,2-Diamines: An Expeditious Route to Enantiopure Tricyclic Amidines.

✍ Scribed by D. Christopher Braddock; Thais Cailleau; Gemma Cansell; Stephen A. Hermitage; Rebecca H. Pouwer; Joanna M. Redmond; Andrew J. P. White

Publisher
John Wiley and Sons
Year
2011
Weight
85 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The condensation—oxidation of dialdehydes (I) and (V) with diamines gives the corresponding 1,3‐ and 1,4‐diamidines.

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Synthesis of Enantiopure 1,4-Dioxanes, Morpholines, and Piperazines from the Reaction of Chiral 1,2-Diols, Amino Alcohols, and Diamines with Vinyl Selenones. -The reaction of enantiopure diols, amino alcohols, or diamines with vinyl selenones in the presence of NaH represents a novel route to the ti