✦ LIBER ✦

ChemInform Abstract: The Preparation and Characterization of SeCl3SbF6, Improved Syntheses of MCl3(As/Sb)F6 (M: S, Se), and X-Ray Crystal Structure Determination of SeCl3AsF6 and a New Phase of SBr3SbF6.

✍ Scribed by J. PASSMORE; T. S. CAMERON; P. D. BOYLE; G. SCHATTE; T. WAY

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199709019

No coin nor oath required. For personal study only.

✦ Synopsis

The Preparation and Characterization of SeCl3SbF6, Improved Syntheses of MCl3(As/Sb)F6 (M: S, Se), and X-Ray Crystal Structure Determination of SeCl3AsF6 and a New Phase of SBr3SbF6.

-SeCl3AsF6 is prepared in 97% yield by reaction of SeCl4 and AsF5 in SO2 and SCl3AsF6 is obtained in 65% yield from S8, AsF3, and Cl2 in SO2. The corresponding reaction of S8, Br2, and SbF5 in SO2 yields SBr3SbF6 (92%). The preferred route to ACl3SbF6 (A: S, Se) with yields of ¿ 90% is the reaction of ASeCl4 (prepared in situ) with AgSbF6. The compounds are characterized by FT-Raman and FT-NMR spectroscopy. According to the single crystal XRD data for SeCl3AsF6 and the new phase SBr3SbF6 these compounds are isostructural, crystallizing in the monoclinic space group P21/c with Z = 4.

-(PASSMORE,

📜 SIMILAR VOLUMES

ChemInform Abstract: X-Ray Crystal Struc

ChemInform Abstract: X-Ray Crystal Structures of α-KrF2, [KrF][MF6] (M: As, Sb, Bi), [Kr2F3][SbF6]×KrF2, [Kr2F3]2 [SbF6]2×KrF2, and [Kr2F3][AsF6]×[KrF] [AsF6]; Synthesis and Characterization of [Kr2F3][PF6]×nKrF2; and Theoretical Studies of KrF2, KrF+, Kr2F3+, and [KrF][MF6] (M: P, As, Sb, Bi) Ion Pairs.

✍ John F. Lehmann; David A. Dixon; Gary J. Schrobilgen 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: The OsO3F+ and μ-F(

ChemInform Abstract: The OsO3F+ and μ-F(OsO3F)+2 Cations: Their Syntheses and Study by Raman and 19F NMR Spectroscopy and Electron Structure Calculations and X-Ray Crystal Structures of [OsO3F][PnF6] (Pn: As, Sb), [OsO3F][HF]2[AsF6], [OsO3F][HF][SbF6], and [OsO3F][Sb3F16].

✍ Michael Gerken; David A. Dixon; Gary J. Schrobilgen 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

ChemInform Abstract: Reactions of Trimet

ChemInform Abstract: Reactions of Trimethylstibine in the Superacidic Systems XF/MF5 (X: H, D; M: As, Sb), Crystal Structures of (CH3)3SbD+SbF-6 and (CH3)3SbSb(CH3)2+3 (SbF-6)2×SO2.

✍ Rolf Minkwitz; Claudia Hirsch 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

ChemInform Abstract: An X-Ray Crystallog

ChemInform Abstract: An X-Ray Crystallographic Study of [Xe2F3][SbF6] and Dimorphism in [Xe2F3][AsF6]; and a Density Functional Theory Study of the Xe2F+3 Cation.

✍ Barbara A. Fir; Michael Gerken; Bernard E. Pointner; Helene P. A. Mercier; D. A. 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

ChemInform Abstract: Fluoride Ion Donor

ChemInform Abstract: Fluoride Ion Donor Properties of TcO2F3 and ReO2F3: X-Ray Crystal Structures of MO2F3×SbF5 (M: Tc, Re) and TcO2F3×XeO2F2 and Raman and NMR Spectroscopic Characterization of MO2F3×PnF5 (Pn: As, Sb), [ReO2F2(CH3CN)2] [SbF6], and [Re2O4F5][Sb2F11].

✍ Nicolas LeBlond; David A. Dixon; Gary J. Schrobilgen 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 2 views

ChemInform Abstract: Preparation, X-Ray

ChemInform Abstract: Preparation, X-Ray Crystal Structure Determination, Lattice Potential Energy, and Energetics of Formation of the Salt S4(AsF6)2×AsF3 Containing the Lattice-Stabilized Tetrasulfur [2+] Cation. Implications for the Understanding of the Stability of X42+ and X2+ (X: S, Se, and Te) Crystalline Salts.

✍ T. Stanley Cameron; Isabelle Dionne; H. Donald Brooke Jenkins; Simon Parsons; Ja 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views