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ChemInform Abstract: The Phototransposition in Acetonitrile and the Photoaddition of 2,2,2-Trifluoroethanol to the Six Isomers of Dimethylbenzonitrile.

โœ Scribed by Nisa Howell; James A. Pincock; Roumiana Stefanova

Publisher
John Wiley and Sons
Year
2000
Weight
26 KB
Volume
31
Category
Article
ISSN
0931-7597

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โœ Johannes Leitich; Ingeborg Heise ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 448 KB ๐Ÿ‘ 1 views

The title reaction has been studied with 2-methoxypropene, (E)-cyclooctene, ethoxyethene, 1,3-cyclopentadiene, 3methylenecyclohexene, styrene and isoprene as the olefinic substrates. This sequence is one of decreasing reactivity of the substrates towards 2-oxido-2-cyclopenten-1-ylium (1) if [4 + 3]