ChemInform Abstract: The para-Toluenesulfonic Acid Promoted Synthesis of 2-Substituted Benzoxazoles and Benzimidazoles from Diacylated Precursors.
β Scribed by M. R. DELUCA; S. M. KERWIN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Stereochemical Change in the Lewis Acid-Promoted Reaction of 2-Siloxypyrrole Derived from (L)-Glutamic Acid. Synthesis of a Lactacystin Analogue. -The enantiopure pyrrolooxazole (I) react with aliphatic aldehydes [cf. (II)] stereoselectively to yield either the isomers (IV) or (VIII) as major produ