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ChemInform Abstract: The Oxidation of Homophthalimide Derivatives by Dioxygen in Alkaline Media and Cleavage-Cyclization Reactions.

✍ Scribed by H. HEANEY; M. O. TAHA; A. M. Z. SLAWIN

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Oxidation of Homophthalimide Derivatives by Dioxygen in Alkaline Media and Cleavage-Cyclization Reactions. -Oxidation of the homophthalimide derivative (Ia) with dioxygen in alkaline ethanolic solution generates the lactone (IIa) almost quantitatively. The analogues (Ib) and (Ic) react more slowly to the hydroxyhomophthalimides (III). The latter can be converted to (IIb) and (IIc) by further refluxing in ethanolic NaOH, suggesting them to be intermediates in the reaction (I) to (II). -(HEANEY, H.;

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