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ChemInform Abstract: The Origin of the β-Lactam Carbons of Clavulanic Acid.

✍ Scribed by J. E. THIRKETTLE; J. E. BALDWIN; J. EDWARDS; J. P. GRIFFIN; C. J. SCHOFIELD

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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The Biosynthesis of Pramanicin: Origin of the Carbon Skeleton. -Incorporation of labeled acetates and serine into pramanicin (I) shows that its carbon skeleton is derived from eight acetate units and a serine residue, implying that the biosynthesis proceeds via an acyl-tetramic acid intermediate.