ChemInform Abstract: The Hydrogen-Bonding System in Deuterated Copper Fluorosilicate Tetrahydrate: A Neutron Diffraction Study.

✍ Scribed by G. CHEVRIER; A. GOUKASSOV

• Book ID: 101840473
• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199704007

✦ Synopsis

The Hydrogen-Bonding System in Deuterated Copper Fluorosilicate Tetrahydrate: A Neutron Diffraction Study. -Single crystal neutron diffraction studies for CuSiF6•4 D2O show that this compound (monoclinic, P21/c, Z = 2) is built-up from regular SiF6 and elongated Cu(D2O)4F2 octahedra which are linked by a common F atom. The thus formed chains are bonded by hydrogen bonds from water molecules of one chain to F atoms of six adjacent chains. -(CHEVRIER, G.;