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ChemInform Abstract: The Highly Diastereoselective Palladium-Catalyzed Cyclizations. Stereoselective Syntheses of cis- and trans-Disubstituted Hydroxycyclopentanes.

✍ Scribed by Y.-G. SUH; J.-K. JUNG; S.-A. KIM; D.-Y. SHIN; K.-H. MIN

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199736089

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✦ Synopsis

The Highly Diastereoselective Palladium-Catalyzed Cyclizations. Stereoselective Syntheses of cis-and trans-Disubstituted Hydroxycyclopentanes.

-The Pd-catalyzed diastereoselective cyclization of (I) produces the bicyclic lactones (II) as the major products. The selective desulfonation of (IIa) provides the hydroxycyclopentane (VI), a valuable precursor of the highly advanced carbaprostacyclin intermediate (VII). -(SUH, Y.-G.;

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