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ChemInform Abstract: The First Pincer-Type Phosphodiamidite Ligand Containing Chiral Phosphorus Atoms.

✍ Scribed by K. N. Gavrilov; E. A. Rastorguev; A. A. Shiryaev; T. B. Grishina; A. S. Safronov; S. E. Lyubimov; V. A. Davankov

Publisher: John Wiley and Sons
Year: 2010
Weight: 21 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201041030

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✦ Synopsis

Abstract

The first pincer‐type phosphodiamidite ligand is synthesized and applied as catalyst ligand in the Pd‐catalyzed enantioselective allylic sulfonylation of ester and carbonate (I) and in the Pd‐catalyzed deracemization of compound (Ib).

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