ChemInform Abstract: The First Experimental Evidence of the Formation of Betaines in the Wittig Reaction.
β Scribed by I. V. BORISOVA; N. N. ZEMLYANSKII; A. K. SHESTAKOVA; YU. A. USTYNYUK
- Book ID
- 112037688
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Reaction of the ylide (cyclopropyl) 3 P=CH 2 with Michler's 3Π) or bis(p-methoxyphenyl) thioketone (to give 5), respectively. The oxaphosphetane series 3Πa-3Πc shows a thioketone S=C(C 6 H 4 NMe 2 ) 2 in [D 5 ]pyridine gave the thio Wittig intermediate [(cyclopropyl) 3 P + -CH 2 -CAr 2 -S -] (11; 31