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ChemInform Abstract: The First Beryllium Periodate: Be(H4IO6)2×4 H2O.

✍ Scribed by Z. ZHANG; H. D. LUTZ; M. GEORGIEV; M. MANEVA

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The First Beryllium Periodate: Be(H4IO6)2•4 H2O. -Single-crystal XRD studies of the title compound, prepared by dissolving BeO in periodic acid and evaporating the aqueous solution obtained, show that they adopt the tetragonal space group I41/acd with Z = 16. The structure is built-up from layers of Be(OH2)4 tetrahedra and double layers of H4IO6 octahedra with the oxo ligands in cis configuration. The layers are connected by hydrogen bonds of different strength formed by two crystallographically different water molecules and four different OH groups of the periodate ion. -(ZHANG, Z.; LUTZ, H.

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