Oxidative polymerization of m-phenylenediamine was carried out using H 2 O 2 as an oxidant and horseradish peroxidase as a catalyst in mixtures of aqueous buffer solution and 1,4-dioxane or in reversed micellar solutions. When the reaction mixture was brought into contact with a stainless steel stic
ChemInform Abstract: The Effect of pH on the Oxidative Polymerization of Aniline and the Morphology and Properties of Products
β Scribed by I. Yu Sapurina; J. Stejskal
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 18 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The aniline molecule is nonplanar, with its NH 2 group lying at an angle ΞΈ of approximately 42 β’ to the plane of the benzene ring. Substituents on the phenyl ring alter this out-of-plane angle as well as other molecular properties such as the ring bond lengths and angles, the barrier to inversion E
The influence of pH on the incorporation of a functional monomer (itaconic acid or methacrylic acid) on core-shell polymers of styrene-butyl acrylate and on their mechanical properties is investigated. The structured polymers were prepared by a two-stage emulsion polymerization process. It was found