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ChemInform Abstract: The Diels—Alder Reactions of Quinone Imine Ketals: A Synthesis of the Ergot Skeleton.

✍ Scribed by Scott C. Banfield; Michael A. Kerr


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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The Diels—Alder Reactions of Quinone Imi
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The High Pressure Diels-Alder Reactions of Quinone-mono-ketals. -Simple quinone-mono-ketals react with nonactivated dienes at high pressure to yield the corresponding adducts. Treatment of these adducts with catalytic acid forms the aromatized products, i.e. the annulated benzenes or naphthalenes.

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