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ChemInform Abstract: The Diammoniate of Diborane: Crystal Structure and Hydrogen Release.

✍ Scribed by Mark Bowden; David J. Heldebrant; Abhi Karkamkar; Thomas Proffen; Gregory K. Schenter; Tom Autrey

Publisher
John Wiley and Sons
Year
2011
Weight
21 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Diammoniate of Diborane: Crystal Structure and Hydrogen Release. -[(NH3)2BH2] + [BH4] -is obtained by room temperature solid state decomposition of an equimolar mixture of NH4BH4 and NH3BH3 (milling, 10 min) and its crystal structure is determined by Rietveld refinement of combined X-ray and neutron powder diffraction data. The compound crystallizes in the space group I4/mcm. The crystal structure contains disordered ions at two distinct sites. Hydrogen release from [(NH3)2BH2] + [BH4] -is similar to that from NH3BH3 but with faster kinetics. -(BOWDEN*, M.; HELDEBRANT, D.

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