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ChemInform Abstract: The Cluster Compounds Ag[W6Br14] and Ag2[W6Br14].

✍ Scribed by Yue-Qing Zheng; Horst Borrmann; Yuri Grin; Karl Peters; Hans Georg von Schnering

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200012006

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The Cluster Compounds Ag[W6Br14] and Ag2

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The reaction of W 6 Br 12 with AgBr in evacuated silica tubes (temperature gradient 925 K/915 K) yielded brownish black octahedra of Ag[W 6 Br 14 ] (I) and yellowish green platelets of Ag 2 [W 6 Br 14 ] (II) both in the low temperature zone. (I) crystallizes cubically (Pn3 (no. 201); a = 13.355 A Ê

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## Abstract The new compound Bi~2~W~6~Br~18~ is synthesized from mixtures of WBr~6~ and elementary Bi (silica tube, 350 °C, 48 h).

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ChemInform Abstract: Syntheses and Crystal Structures of the Cluster Compounds M2 [(W6Br8i)Br6a] with M: K, Rb, Cs.

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ChemInform Abstract: Two Modifications of Copper(I) Octahedro-hexatungsten(II) Tetradecabromide, Cu2[W6Br14].

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Assisted Crystallization of Organometallic Cations by Interplay with Inorganic Anionic Clusters Units: Synthesis and Characterizations of the [Cp*(dppe)Fe–NCMe]2·M6L14 Series (M6L14 = Cluster Unit: [Re6S6Br8]2–, [Mo6Br14]2– and [Mo6I14]2–)

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