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ChemInform Abstract: The Chemistry of the Highly Reactive 2,6-Bis(bromomethyl)-4-pyrone.

✍ Scribed by Werner Loewe; Stefanie A. Braetter; Manuela Weber; Peter Luger; Joachim Buddrus

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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The chemistry of the highly reactive 2,6
The chemistry of the highly reactive 2,6-bis(bromomethyl)-4-pyrone
✍ Werner LΓΆwe; Stefanie A. BrΓ€tter; Manuela Weber; Peter Luger; Joachim Buddrus πŸ“‚ Article πŸ“… 2001 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 66 KB

## Abstract Under basic conditions 2,6‐bis(bromomethyl)‐4‐pyrone **8** reacts with tetraethylene glycol to yield the unexpected macrocycle **9**, which is related to the antibiotic Kjellmanianone **10**. We propose that this ring transformation proceeds __via__ the cyclopropyl intermediate **d** (S

The solvates of 1,2-bis(bromomethyl)-3,4
The solvates of 1,2-bis(bromomethyl)-3,4,5,6-tetraphenylbenzene
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Solvates of 1,2-bis(bromomethyl)-3,4,5,6-tetraphenylbenzene (1) were obtained, and their crystal structures were determined by X-ray diffraction. Crystal structure analysis indicated the following chemical compositions of solvates: 1AEbenzene (2), 1AE1/2 toluene (3), 1AE1/2 chlorobenzene (4) and 1AE