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ChemInform Abstract: The Biomimetic Construction of Fused Cyclic Polyethers.

✍ Scribed by N. HAYASHI; K. FUJIWARA; A. MURAI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Biomimetic Construction of Fused Cyclic Polyethers.

-The biomimetic synthesis of naturally occurring fused cyclic ethers by successive ring closure methods is investigated for simple model systems. The one-pot successive ring expansion reactions of bromo trans,trans-diepoxides promoted by AgOTf leads to cis-fused bicyclic ethers such as (XVI) and (XVIII) regardless of the relative configurations between the epoxy groups. -(HAYASHI, N.;

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