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ChemInform Abstract: The Acid-Induced Rearrangement of 1-Hydroxyalkyltris(trimethylsilyl)silanes

✍ Scribed by K. STERNBERG; H. OEHME


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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πŸ“œ SIMILAR VOLUMES


The Acid-Induced Rearrangement of 1-Hydr
✍ Katrin Sternberg; Hartmut Oehme πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 421 KB

In the presence of strong acids, such as HCl or H 2 SO 4 , 1-Si(OSO 3 H)ΟͺC(SiMe 3 )HMes (5) was isolated. 5 is the intermediate in the H 2 SO 4 -catalyzed isomerization of 1d and was hydroxyalkyltris(trimethylsilyl)silanes (Me 3 Si) 3 SiΟͺC(OH)R 1 -R 2 (1a؊f) isomerize by 1,2-Me 3 Si/OH exchange to g